list of magnesium alloys
Some success has also been achieved with laser welding and with friction stir welding (Section 4.5.1) and both these methods have been used experimentally to join dissimilar magnesium alloys or magnesium alloys to aluminium alloys. The plastic forging range is 500 to 800 °F (260 to 427 °C). Magnesium alloys are referred to by short codes (defined in ASTM B275) which denote approximate chemical compositions by weight. Therefore, except for one or two soft alloys, machining is invariably a preliminary step before other shaping processes. To assure proper adherence of the paint, the part is cleaned by grinding, buffing, or blasting, then given an acid dichromate dip. Alloys AZ31, AZ61 and AZ80 are employed for extrusions in the order named, where increase in strength justifies their increased relative costs. In recent years, FSW has been extensively used for joining a spectrum of magnesium alloys. Aluminium is the most common alloying element. In coarse material, larger particles of the compounds are present that are less readily dissolved, and tend to cause a solution gradient. [citation needed] It is necessary, however, to keep the tools sharp and to provide ample space for the chips. [15] The higher oxidation reactivity of calcium causes a coat of calcium oxide to form before magnesium ignites. • AA-8000: used for electrical building wire in the U.S. per the National Electrical Code, replacing AA-1350. Inhibitors such as sulfur, boric acid, ethylene glycol, or ammonium fluoride are mixed with the damp sand to prevent the reaction. Both precipitates are observed in peak-aged specimens. The designation system for magnesium alloys is not as well standardized as in the case of steels or aluminium alloys; most producers follow a system using one or two prefix letters, two or three numerals, and a suffix letter. by principal alloy composition: •Magnesium-manganese (M) •Magnesium-aluminum-manganese (AM) •Magnesium-aluminum-zinc-manganese. Applications for magnesium alloys in current Boeing planes like 737 and 747 are limited to a few components like small wing components and parts of the doors. Magnesium alloys are typically used as cast alloys; however, research on wrought alloys has shown tremendous growth during the last decade. The most common wrought magnesium alloys are: AZ31, AZ61, AZ80, Elektron 675, ZK60, M1A, HK31, HM21, ZE41, and ZC71. [10][full citation needed], Scandium and gadolinium have been tried as alloying elements; an alloy with 1% manganese, 0.3% scandium and 5% gadolinium offers almost perfect creep resistance at 350C. [13] Magnesium-lithium alloys are generally soft and ductile, and the density of 1.4 g/cm3 is appealing for space applications. Magnesium alloys can be spot-welded nearly as easily as aluminium, but scratch brushing or chemical cleaning is necessary before the weld is formed. Magnesium (Mg) alloys are promising structural materials for the automotive, aerospace and electronic industries. Magnesium (Mg) alloys are promising structural materials for the automotive, aerospace and electronic industries. Considerable misinformation exists regarding the fire hazard in processing magnesium alloys. Magnesium (Mg) alloys are expected to be biodegradable metals for use in stents and artificial bones. ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. URL: https://www.sciencedirect.com/science/article/pii/B9780128120682000072, URL: https://www.sciencedirect.com/science/article/pii/B9780080994314000063, URL: https://www.sciencedirect.com/science/article/pii/B9781845697082500111, URL: https://www.sciencedirect.com/science/article/pii/B9781845696924500171, URL: https://www.sciencedirect.com/science/article/pii/B9780857094377500077, URL: https://www.sciencedirect.com/science/article/pii/B9780857090881500045, URL: https://www.sciencedirect.com/science/article/pii/B9781845699680500053, URL: https://www.sciencedirect.com/science/article/pii/B9780128161319000027, URL: https://www.sciencedirect.com/science/article/pii/B9781845694340500012, URL: https://www.sciencedirect.com/science/article/pii/B9780124114678000155, Surface Modification of Magnesium and its Alloys for Biomedical Applications, 2015, Krishnan K. Sankaran, Rajiv S. Mishra, in, Metallurgy and Design of Alloys with Hierarchical Microstructures, Corrosion of magnesium (Mg) alloys in engine coolants. All the alloys may be used for more than one product form, but alloys AZ63 and AZ92 are most used for sand castings, AZ91 for die castings, and AZ92 generally employed for permanent mold castings (while AZ63 and A10 are sometimes also used in the latter application as well). By continuing you agree to the use of cookies. Soldering of magnesium alloys is feasible only for plugging surface defects in parts. Using –F, -O, -H1, -T4, -T5, and –T6. The US Army Research Laboratory had organized a Sagamore Conference on Lightweight Materials in 2010. Magnesium alloys are well known for their high strength-to-weight ratios. If a magnesium fire should start, it can be smothered with cast-iron turnings or dry sand, or with other materials prepared especially for the purpose. The most common cast magnesium alloys are: AZ63, AZ81, AZ91, AM50, ZK51, ZK61, ZE41, ZC63, HK31, HZ32, QE22, QH21, WE54, WE43, and Elektron 21. Tube extrusion in alloys AM503, ZW2, and ZW3 is now made with bridge dies. In magnesium alloys, this causes internal stress, since solution is accompanied by a small contraction, and it can also influence the evenness of response to later heat treatment. It should be noted that DRX in magnesium alloys occurs in a highly specific manner due to the strong relationship between DRX mechanisms and deformation mechanisms (Xu et al., 2009a). MAO coating has proved effective in insulating or blocking direct contact between Mg alloys and other metals, thus eliminating galvanic corrosion (Gordienko et al., 1993; Xue et al., 2007; Barchiche et al., 2008; Ghasemi et al., 2008). If these metals, such as iron, nickel and copper, have a low hydrogen over-voltage, they can serve as efficient cathodes, consequently causing severe galvanic corrosion. Mathaudhu [1] also included the example of the H-19 “Chickasaw” built in 1951. One important binary alloy, containing up to 2.0% manganese, is used extensively for the manufacture of rolled sheet. The power required in cutting them is small, and extremely high speeds (5000 ft per min in some cases) may be used. Extrusions of rapidly solidified powders reach tensile strengths of up to 740 MPa due to their amorphous character,[4] which is twice as strong as the strongest traditional magnesium alloys and comparable to the strongest aluminium alloys. Magnesium alloys have a hexagonal lattice structure, which affects the fundamental properties of these alloys. The Journal of Magnesium and Alloys provides an international medium for the publication of theoretical and experimental studies in magnesium science and engineering. Furthermore, studies have shown that formabilit… In the near future, magnesium alloys may become important engine materials for the automotive industry. Magnesium alloys are mixtures of magnesium with other metals (called an alloy), often aluminium, zinc, manganese, silicon, copper, rare earths and zirconium. Above 800 °F (427 °C), a non-combustible, oxygen-free atmosphere is required to suppress burning. It can be seen from Fig. Billet temperatures are also affected by the size of the sections, being higher for heavy reductions, but are usually in the range 250–450 °C (482–842 °F). On the other hand, higher Y content increases the elongation of the alloys but results in decreased strength.[1]. Magnesium alloys have attracted renewed interest as light alloys, to substitute some conventional structural materials for weight reduction in vehicles such as cars, trucks, trains and aircrafts. Good surface condition of the extrusion is achieved only with high speeds, of the order of 50–100 ft. per minute. In addition, strength at ambient temperature can be improved significantly through grain refinement in accordance with the Hall-Petch relationship. Their formability increases with increasing temperature, but that requires high energy. The oxide forms blackened areas called burns on the surface of the casting, and the liberated hydrogen may cause porosity. For significant enhancement of mechanical properties in magnesium alloys, grain refinement to the micron or submicron level is required (Somekawa et al., 2009, Singh et al., 2011). These numbers are very significant and demonstrative of the position magnesium alloys enjoyed during the initial period of aircraft development. T. Hanawa, in Metals for Biomedical Devices, 2010. Technical difficulties in the removal of chloride inclusions from the manufactured metal delayed progress in the development and engineering uses of magnesium and its alloys in the period when a great advance was being made in the application of aluminium base alloys. The machinability of magnesium alloys is the best of any commercial metal, and in many applications, the savings in machining costs more than compensate for the increased cost of the material. Nickel Alloys 5. Metal worked outside this range is easily broken. Static recrystallization (SRX) is widely used in the rolling of magnesium alloys to provide softening between passes. The design of mechanical joints in magnesium and its alloys is qualified by the vital consideration of galvanic corrosion.
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